Title | Low-N lines of the A(6)Sigma(+)-X-6 Sigma(+) (1,0) band of CrH |
Publication Type | Journal Article |
Year of Publication | 2006 |
Authors | Chowdhury, PK, Merer, AJ, Rixon, SJ, Bernath, PF, Ram, RS |
Journal | Physical Chemistry Chemical Physics |
Volume | 8 |
Pagination | 822-826 |
Date Published | Feb |
Type of Article | Article |
ISBN Number | 1463-9076 |
Keywords | LASER MAGNETIC-RESONANCE, SPECTRUM, STATE, SYSTEM, TRANSFORM EMISSION-SPECTROSCOPY, TRANSITION |
Abstract | {The (1,0) band of the A(6)Sigma(+) - X-6 Sigma(+) electronic transition of CrH has been observed by laser-induced fluorescence following the reaction of laser-ablated Cr atoms with methanol under supersonic free-jet cooled conditions. Rotational assignments of the levels with N <= 3 have been made by combination differences and dispersed fluorescence experiments on selected lines. These assignments complement those made from previously-recorded Fourier transform emission spectra, in which higher-N lines were assigned. The low-N rotational levels are extensively perturbed, presumably by levels of the a(4)Sigma(+) |
URL | <Go to ISI>://000235811100004 |