Title | Magnetic susceptibility of aqueous tert-butanol |
Publication Type | Journal Article |
Year of Publication | 1999 |
Authors | Mizuno, K, Ochi, T, Shimada, S, Nishimura, Y, Maeda, S, Koga, Y |
Journal | Physical Chemistry Chemical Physics |
Volume | 1 |
Pagination | 133-135 |
Date Published | Jan |
Type of Article | Article |
ISBN Number | 1463-9076 |
Keywords | 2-BUTOXYETHANOL, 25-DEGREES-C, ALCOHOL-SOLUTIONS, BUTYL ALCOHOL, COMPRESSIBILITIES, EXTERNAL REFERENCING METHOD, MIXTURES, NONELECTROLYTES, PARTIAL MOLAR ENTHALPIES, REGION, WATER-RICH |
Abstract | Magnetic susceptibilities of aqueous tert-butanol were measured by the external double reference NMR method of Momoki and Fukazawa.(1,2) Reflecting a non-ideal volumetric behaviour of this mixture the volume susceptibility data shows a large non-ideal composition dependence. On the other hand, the molar magnetic susceptibility exhibits a small but finite deviation from ideality. Thus, an intra-molecular property, diamagnetic susceptibility, is not completely free from the effect of a non-ideal molecular arrangement in the mixture. |
URL | <Go to ISI>://000079350200019 |
