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  3. METAL PYRAZOLATE POLYMERS .2. SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF [CU(4-CL PYRAZOLATE)2)X, (CU(4-BR PYRAZOLATE)2)X, (CU(4-ME PYRAZOLATE)2)X, (CU(4-H PYRAZOLATE)2)X POLYMERS

METAL PYRAZOLATE POLYMERS .2. SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF [CU(4-CL PYRAZOLATE)2)X, (CU(4-BR PYRAZOLATE)2)X, (CU(4-ME PYRAZOLATE)2)X, (CU(4-H PYRAZOLATE)2)X POLYMERS

TitleMETAL PYRAZOLATE POLYMERS .2. SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF [CU(4-CL PYRAZOLATE)2)X, (CU(4-BR PYRAZOLATE)2)X, (CU(4-ME PYRAZOLATE)2)X, (CU(4-H PYRAZOLATE)2)X POLYMERS
Publication TypeJournal Article
Year of Publication1991
AuthorsEhlert, MK, Rettig, SJ, Storr, A, Thompson, RC, Trotter, J
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume69
Pagination432-439
Date PublishedMar
Type of ArticleArticle
ISBN Number0008-4042
KeywordsCOPPER(II), COPPER(II) 4-SUBSTITUTED PYRAZOLATE POLYMERS, crystal structures, MAGNETIC EXCHANGE
Abstract

{Novel and reliable methods for the synthesis of the polymers [Cu(4-Xpz)2]x (where X = H,Cl,Br, and Me; pz = pyrazolate) are presented. The X = Cl compound was obtained as green and brown forms. Single crystals of the polymers with X = Me and X = Cl (green form) suitable for X-ray analysis have been obtained. [Cu(4-Mepz)2]x and [Cu(4-Clpz)2]x are isomorphous, crystallizing with four formula units per unit-cell in the orthorhombic space group Ibam
URL<Go to ISI>://A1991FE80800010