Title | Microwave Fourier transform spectroscopy of magnesium sulfide produced by laser ablation |
Publication Type | Journal Article |
Year of Publication | 1997 |
Authors | Walker, KA, Gerry, MCL |
Journal | Journal of Molecular Spectroscopy |
Volume | 182 |
Pagination | 178-183 |
Date Published | Mar |
Type of Article | Article |
ISBN Number | 0022-2852 |
Keywords | MGS, SPECTRA |
Abstract | The pure rotational spectrum of magnesium sulfide has been measured with a cavity pulsed microwave Fourier transform (MWFT) spectrometer, as a test of a new laser ablation source. The J = 1-0 transition near 16 GHz has been measured for 4 isotopomers in the ground vibrational slate, as well as for the main isotopomer, (MgS)-Mg-24-S-32, in the first excited vibrational state. Mg-25 nuclear hyperfine structure has been observed and the nuclear quadrupole coupling constant, eQq(Mg-25), has been determined. A value for the equilibrium bond length has been obtained. (C) 1997 Academic Press. |
URL | <Go to ISI>://A1997WN85400017 |