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Molecular architectures for trimetallic d/f/d complexes: Structural and magnetic properties of a LnNi(2) core

TitleMolecular architectures for trimetallic d/f/d complexes: Structural and magnetic properties of a LnNi(2) core
Publication TypeJournal Article
Year of Publication2008
AuthorsBarta, CA, Bayly, SR, Read, PW, Patrick, BO, Thompson, RC, Orvig, C
JournalInorganic Chemistry
Volume47
Pagination2280-2293
Date PublishedApr
ISBN Number0020-1669
Abstract

{A series of cationic, trimetallic d/f/d complexes have been prepared which use a multiclentate, macrocyclic amine phenol ligand to coordinate divalent first row d-block transition metal ions (TM) and lanthanides (Ln) ions in close proximity, desirable for magnetic studies. Isolable complexes of the d/f/d cluster compounds with the formula [Ln(TM)(2)(bcn)(2)]ClO4 center dot nH(2)O, where H(3)bcn is tris-N,N’N"-(2-hydroxybenzyl)-1,4,7-triazacyclononane
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