Title | MOLECULAR-HYDROGEN, MOLECULAR-NITROGEN AND MONOHYDRIDE DERIVATIVES OF THE STRUCTURALLY CHARACTERIZED DICHLORO(O-DIPHENYLPHOSPHINO-N,N-DIMETHYLANILINE)[TRIS(P-TOLYL)PHOSPHINE ]RUTHENIUM(II) COMPLEX |
Publication Type | Journal Article |
Year of Publication | 1993 |
Authors | Mudalige, DC, Rettig, SJ, James, BR, Cullen, WR |
Journal | Journal of the Chemical Society-Chemical Communications |
Pagination | 830-832 |
Date Published | May |
Type of Article | Article |
ISBN Number | 0022-4936 |
Keywords | DIHYDROGEN, LIGANDS, ruthenium |
Abstract | The crystallographically characterised, five-coordinate complex [RuCl2(o-diphenylphosphino-N,N-dimethylaniline){P(p-tolyl)3}] reversibly binds H-2 and N2 to form eta2-H-2 and sigma-N2 species, respectively; the former reacts with base to generate the chloro(hydrido) derivative. |
URL | <Go to ISI>://A1993LD66800010 |
