Title | MUON SPIN RELAXATION STUDIES OF CYCLOHEXADIENYL RADICALS IN NAUSY |
Publication Type | Book Chapter |
Year of Publication | 1994 |
Authors | Shelley, M, Arseneau, DJ, Senba, M, Pan, JJ, Snooks, R, Kreitzman, SR, Fleming, DG, Roduner, E |
Editor | Weitkamp, J, Karge, HG, Pfeifer, H, Holderich, W |
Book Title | Zeolites and Related Microporous Materials: State of the Art 1994 |
Series Title | Studies in Surface Science and Catalysis |
Volume | 84 |
Pagination | 469-475 |
Publisher | Elsevier Science Publ B V |
City | Amsterdam |
ISBN Number | 0-444-81847-2 |
Keywords | benzene, DIFFUSION, LEVEL-CROSSING RESONANCE, LOCALIZATION, MOLECULAR-DYNAMICS, NAX, NMR, NUCLEAR MAGNETIC-RESONANCE, SODIUM-Y ZEOLITE |
Abstract | The avoided level crossing muon spin resonance (ALC-mu SR) technique is a promising new tool that can be used as a highly sensitive microscopic probe of radical motions in zeolites. We report a recent experiment in which this technique was used to identify a muonated cyclohexadienyl radical (C(6)H(6)Mu) and explore its reorientational dynamics in NaUSY. The observed evolution of the Delta M=1 ALC resonance lines are interpreted in terms of the site exchange dynamics of the radical. |
URL | <Go to ISI>://A1994BD02E00057 |