| Title | A NEW CYCLOPENTENONE ANNULATION METHOD |
| Publication Type | Journal Article |
| Year of Publication | 1994 |
| Authors | Piers, E, Cook, KL, Rogers, C |
| Journal | Tetrahedron Letters |
| Volume | 35 |
| Pagination | 8573-8576 |
| Date Published | Nov |
| Type of Article | Article |
| ISBN Number | 0040-4039 |
| Keywords | ACID, ALCOHOLS |
| Abstract | Alkylation of the substrates 8-12 with (Z)-3-bromo-1-iodopropene (5), followed by n-Buli-mediated cyclization of the resultant products 15-19, provides the tertiary allylic alcohols 22-26, which, upon oxidation with a Cr(VI) reagent, afford the cyclopentenones 29-33. The alpha-methylcyclopentenones 34 and 35 are similarly derived from the kero esters 13 and 14. |
| URL | <Go to ISI>://A1994PT04700016 |
