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Nitrogenous educts through oxidative amidation of phenols: The bimolecular reaction

TitleNitrogenous educts through oxidative amidation of phenols: The bimolecular reaction
Publication TypeJournal Article
Year of Publication2005
AuthorsCanesi, S, Bouchu, D, Ciufolini, MA
JournalOrganic Letters
Volume7
Pagination175-177
Date PublishedJan
Type of ArticleArticle
ISBN Number1523-7060
Keywords(-)-TAN1251A, AMIDES, AMINATION, ARENES, CYCLIZATION, DERIVATIVES, FR901483, HYPERVALENT IODINE OXIDATION, N-ACYLNITRENIUM IONS, TYROSINE
Abstract

The elusive oxidative amidation of phenols to 4-aza-substituted dienones in the bimolecular mode may be achieved by treatment with iodobenzene diacetate ("DIB") in a mixture of hexafluoro-2-propanol and acetonitrile.
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