Title | Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(III) phosphoramidate complex |
Publication Type | Journal Article |
Year of Publication | 2017 |
Authors | Drover, MW, Schafer, LL, Love, JA |
Journal | DALTON TRANSACTIONS |
Volume | 46 |
Pagination | 8621-8625 |
Date Published | JUL 14 |
ISSN | 1477-9226 |
Abstract | The reaction of a Cp{*}Ir(III) phosphoramidate complex with secondary amines gives amine, imine-bound Cp{*}Ir(III) hydride complexes resulting from amine dehydrogenation. These well-characterized species could serve as models of relevant intermediates that have been proposed in catalytic amine dehydrogenation using related N, O-chelated Cp{*}Ir(III) pyridonate complexes. |
DOI | 10.1039/c7dt01499f |
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