Title | Formation of hexacarbonylmanganese(I) salts, [Mn(CO)(6)]X-+(-), in anhydrous HFII |
Publication Type | Journal Article |
Year of Publication | 2007 |
Authors | Geier, J, Willner, H, Lehmann, CW, Aubke, F |
Journal | Inorganic Chemistry |
Volume | 46 |
Pagination | 7210-7214 |
Date Published | Aug |
ISBN Number | 0020-1669 |
Abstract | {A convenient one-step synthesis for [Mn(CO)(6)](+) salts has been developed. The method involves the one-electron oxidation of Mn-2(CO)lo by protons in solutions of Lewis acids (BF3, (CF3)(3)BCO) and anhydrous HF. The molecular structure of [Mn(CO)(6))[BF4]center dot SO2 was determined by single-crystal X-ray diffraction. Crystal data: orthorhombic, space group Cmc2(1); a = 8.7001(2) angstrom |
URL | <Go to ISI>://000248757200055 |
![](https://chem.ubc.ca/sites/default/files/styles/header_large_c/public/header_images/ugradlab-header.jpg?itok=-FidXx5L×tamp=1585256910)