Title | THERMOLYSIS OF OS3(CO)10[FE(ETA-C5H4PPRI2)2] - CRYSTAL AND MOLECULAR-STRUCTURES OF (MU-H)OS3(CO)8[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRICHMECH2CO)], (MU-H)OS3(CO)9[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRI)], AND (MU-H)2OS3(CO)8[ETA-3-MU-(ETA-C5H4PPRI2)FE(ETA-C5H3PPRI |
Publication Type | Journal Article |
Year of Publication | 1993 |
Authors | Cullen, WR, Rettig, SJ, Zheng, TC |
Journal | Organometallics |
Volume | 12 |
Pagination | 688-696 |
Date Published | Mar |
Type of Article | Article |
ISBN Number | 0276-7333 |
Keywords | COMPLEXES, COORDINATION, OSMIUM, TRIOSMIUM CLUSTERS, X-ray structures |
Abstract | {The pyrolysis of Os3(CO)10[Fc’(PPri2)2] (Fc’ = (17-C5H4)2Fe) in octane for 7.5 h affords (mu-H)Os3(CO)8[mu-(eta-C5H4Pri2)Fe(eta-C5PriCHMeCH2CO)], 5, (mu-H)Os3(CO)9[mu-(eta-C5H4PPri2)Fe(eta-C5H4PPri)], 6, (mu-H)2083(CO)8[mu-[eta-C5H4Pri2)Fe(eta-C5H3PPri)], 7, (mu-H)083(CO)8[mu-(eta-C5H4PPri2) Fe(eta-C5H4PPriCHMeCH2CO)], 8, (mu-H)2083(CO)8[(eta-C5H4PPri2)Fe(eta-C5H3PPri)], 9, and (A-H)2Os3(CO)8[(eta-C5H4PPri)Fe(eta-C5H3PPri2)],10. X-ray data: 5,monoclinic,space group P2(1)/a (No. 14) |
URL | <Go to ISI>://A1993KR05600019 |
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