Title | DOUBLE METALATION AND IRON OSMIUM BONDING INVOLVING FERROCENYL MOIETIES ON CLUSTERS - CRYSTAL AND MOLECULAR-STRUCTURES OF H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PPRI2)] AND H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PFCET)] |
Publication Type | Journal Article |
Year of Publication | 1992 |
Authors | Cullen, WR, Rettig, SJ, Zheng, TC |
Journal | Organometallics |
Volume | 11 |
Pagination | 3434-3439 |
Date Published | Oct |
Type of Article | Article |
ISBN Number | 0276-7333 |
Keywords | ATOMS, COMPLEXES, FE, PD(BF4)2 |
Abstract | {Thermolysis of Os3(CO)11(PFcPR2i) and Os3(CO)11(PEtFc2) (FcH = Fe(eta-C5H5)2) affords the title compounds, {mu3-[(eta-C5H4)Fe(eta-C5H3PPr2i)]}(mu-H)2Os3(CO)8 (7) and {mu3-[(eta-C5H4)Fe(eta5H3PEtFc)]}(mu-H)2Os3(CO)8 (8), in 15 and 25% yield, respectively. The structures of 7 and 8 are very similar and they both contain a doubly metalated ferrocenyl moiety, the iron atom of which is bonded to one osmium atom m the cluster. 7: triclinic |
URL | <Go to ISI>://A1992JT75400050 |
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