Title | AN UNPRECEDENTED DERIVATIVE OF BENZYNECHROMIUM TRICARBONYL, RU3(CO)8[MU-3-C6H4CR(CO)3][MU-3-PBU-TERT] |
Publication Type | Journal Article |
Year of Publication | 1992 |
Authors | Cullen, WR, Rettig, SJ, Zhang, HL |
Journal | Organometallics |
Volume | 11 |
Pagination | 1000-1002 |
Date Published | Feb |
Type of Article | Note |
ISBN Number | 0276-7333 |
Keywords | CRYSTAL |
Abstract | {The reaction of Ru3(CO)12 with P[C6H5Cr-(CO)3]2Bu(t) affords the benzynechromium tricarbonyl derivative Ru3(CO)8[mu3-C6H4Cr(CO)3][mu(3)-PBu(t)] (5). The aryne is bound symmetrically to the closed Ru3 cluster, and the eta(2)-bound carbon atoms are four-electron donors. In addition, there is a Ru –> Cr bond of length 2.920 (1) angstrom. 5: monoclinic, P2(1)/a |
URL | <Go to ISI>://A1992HE29800082 |
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