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Synthesis of functional phosphines with ortho-substituted aryl groups: 2-RC6H4PH2 and 2-RC6H4P(SiMe3)2 (R = 2-i-Pr- or 2-t-Bu-).

TitleSynthesis of functional phosphines with ortho-substituted aryl groups: 2-RC6H4PH2 and 2-RC6H4P(SiMe3)2 (R = 2-i-Pr- or 2-t-Bu-).
Publication TypeJournal Article
Year of Publication2010
AuthorsDugal-Tessier, J, Kuhn, P-S, Dake, GR, Gates, DP
JournalHeteroatom Chemistry
Volume21
Pagination265 - 270
Date Published2010///
ISBN Number1042-7163
Keywordsphosphine aryl ortho substituted prepn
Abstract

The synthesis and characterization of 2-i-PrC6H4PCl2, 2-t-BuC6H4PCl2, 2-i-PrC6H4PH2, 2-t-BuC6H4PH2, 2-i-PrC6H4P(SiMe3)2, and 2-t-BuC6H4P(SiMe3)2 are described. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:265-270, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20606. [on SciFinder(R)]