Title | PHOSPHINE COMPLEXES OF THE EARLY METALS AND THE IANTHANOIDS |
Publication Type | Journal Article |
Year of Publication | 1991 |
Authors | Fryzuk, MD, Haddad, TS, Berg, DJ, Rettig, SJ |
Journal | Pure and Applied Chemistry |
Volume | 63 |
Pagination | 845-850 |
Date Published | Jun |
Type of Article | Proceedings Paper |
ISBN Number | 0033-4545 |
Keywords | DERIVATIVES, F-BLOCK METALS, FLUXIONAL BEHAVIOR, GROUP-4, HAFNIUM(IV), LIGANDS, RAY CRYSTAL-STRUCTURE, ZIRCONIUM(IV) |
Abstract | The coordination chemistry of the mixed-donor tridentate ligand -N(SiMe2CH2PR2)2 with the early transition metals of groups 3 and 4 and the lanthanide elements will be presented. This ancillary ligand has allowed for the formation of phosphine complexes of these hard elements which has in turn induced new reactivity patterns for hydrocarbyl ligands. |
URL | <Go to ISI>://A1991FN25500008 |