Title | Novel synthetic routes to the anionic alkylidene complex [Cp*Mo(NO)(CH(2)SiMe(3))(=CHSiMe(3))](-) from its neutral dialkyl precursor |
Publication Type | Journal Article |
Year of Publication | 1996 |
Authors | Legzdins, P, Sayers, SF |
Journal | Organometallics |
Volume | 15 |
Pagination | 3907-3909 |
Date Published | Sep |
Type of Article | Article |
ISBN Number | 0276-7333 |
Keywords | DERIVATIVES, H BOND ACTIVATION, LIGAND, lithium, {DECOMPOSITION |
Abstract | Conversion of the dialkyl nitrosyl complex Cp*Mo(NO)(CH(2)SiMe(3))(2) (1) to the lithium salt of the anionic alkylidene complex [Cp*Mo(NO)(CH(2)SiMe(3))(=CHSiMe(3))](2)[Li-2(THF)(3)] (2) may be effected with each of the lithium reagents LiN(SiMe(3))(2), LDA, or LiPPh(2). Interestingly, each transformation follows a different mechanistic pathway. |
URL | <Go to ISI>://A1996VH29300002 |