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Nuclear magnetic resonance studies of helical dipyrromethene-zinc complexes

TitleNuclear magnetic resonance studies of helical dipyrromethene-zinc complexes
Publication TypeJournal Article
Year of Publication2000
AuthorsThompson, A, Dolphin, D
JournalOrganic Letters
Volume2
Pagination1315-1318
Date PublishedMay
Type of ArticleArticle
ISBN Number1523-7060
Keywordschirality, LIGANDS, NMR, RESOLUTION, SHIFT-REAGENTS
Abstract

Analysis of helical chirality within dinuclear dipyrromethene-Zn(II) complexes has been achieved with the use of H-1 NMR spectroscopy. The use of AgFOD and chiral lanthanide shift reagents gives fully resolved resonances attributable to two diastereomeric helical complexes.

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