Title | OLIGOMETALLIC COBALT 3,5-DIMETHYLPYRAZOLATE COMPLEXES - SYNTHESIS, STRUCTURAL AND MAGNETIC STUDIES |
Publication Type | Journal Article |
Year of Publication | 1993 |
Authors | Ehlert, MK, Rettig, SJ, Storr, A, Thompson, RC, Trotter, J |
Journal | Canadian Journal of Chemistry-Revue Canadienne De Chimie |
Volume | 71 |
Pagination | 1425-1436 |
Date Published | Sep |
Type of Article | Article |
ISBN Number | 0008-4042 |
Keywords | CRYSTAL-STRUCTURE, LOW-SPIN, METAL PYRAZOLATE POLYMERS, MOLECULAR-STRUCTURE, THIOCYANATE COORDINATION-COMPOUNDS, TRANSITION |
Abstract | {Three oligometallic 5-dimethylpyrazolate (dmpz) bridged Co(II) compounds have been synthesized and characterized spectroscopically: dimeric [Co(dmpz)2(Hdmpz)]2. the related oligometallic compound, Co(dmpz)2 . 0.344(Hdmpz), and the trimetallic [Co(dmpz)2Cl(Hdmpz)]2Co. The first and last of these compounds have been studied magnetically and by single crystal X-ray diffraction. Crystals of [Co(dmpz)2(Hdmpz)]2 are orthorhombic, = 17.022(1) |
URL | <Go to ISI>://A1993MC95700021 |