Title | ORGANOMETALLIC OXIDES - PREPARATION AND PROPERTIES OF THE TETRAHEDRAL (TD) CUBANE [(ETA-C5(CH3)5)CR(MU-3-O)]4 AND COMPARISON WITH THE D2 [(ETA-C5H5)CR(MU-3-O)]4 AND D2D [(ETA-C5H4CH3)CR(MU-3-O)]4 |
Publication Type | Journal Article |
Year of Publication | 1991 |
Authors | Bottomley, F, Chen, JH, Macintosh, SM, Thompson, RC |
Journal | Organometallics |
Volume | 10 |
Pagination | 906-912 |
Date Published | Apr |
Type of Article | Article |
ISBN Number | 0276-7333 |
Keywords | (ETA-5-C5H5)4CR4O4, ANTI-FERROMAGNETIC COMPLEXES, CLUSTERS, METAL-METAL BONDS, MOLECULAR-STRUCTURES, TETRAHYDROFURAN |
Abstract | {The cubane [(eta-C5(CH3)5)Cr(mu-3-O)]4 (3) was prepared by the reaction between (eta-C5(CH3)5)2Cr (4) and N2O (1:1 molar ratio) in toluene at 80-degrees-C. The structures of 3 and 4 have been determined by X-ray diffraction. 3: M(r) = 813.0, triclinic, P1BAR |
URL | <Go to ISI>://A1991FG97600021 |
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