| Title | Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C−H) Agostic Complex |
| Publication Type | Journal Article |
| Year of Publication | 2016 |
| Authors | D. Beattie, D, Bowes, EG, Drover, MW, Love, JA, Schafer, LL |
| Journal | Angewandte Chemie International Edition |
| Pagination | n/a–n/a |
| ISSN | 1521-3773 |
| Keywords | agostic complexes, AIM calculations, amidate, NICKEL, redox states |
| Abstract | Amidate-supported two- and three-coordinate NiI complexes were synthesized by reduction of the corresponding NiII precursors. A dramatic change in binding mode is observed upon reduction from NiII to NiI. The NiI derivatives include an unprecedented NiI bis(C−H) agostic complex and a two-coordinate NiI complex. |
| URL | http://dx.doi.org/10.1002/anie.201607243 |
| DOI | 10.1002/anie.201607243 |
