| Title | Oxidative addition of thiols to (CO)3Mo(μ-dppm)2Ru(CO)3 with formation of hydrido, bridged-thiolate complexes (dppm = Ph2PCH2PPh2). |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Khorasani-Motlagh, M, Safari, N, Pamplin, CB, Patrick, BO, James, BR |
| Journal | Inorganica Chimica Acta |
| Volume | 363 |
| Pagination | 779 - 783 |
| Date Published | 2010/// |
| ISBN Number | 0020-1693 |
| Keywords | crystal structure ruthenium molybdenum methanediphosphine thiolate hydride heterodinuclear complex, oxidative addn thiol ruthenium molybdenum methanediphosphine heterodinuclear complex, ruthenium molybdenum methanediphosphine thiolate hydride heterodinuclear complex prepn structure |
| Abstract | The room temp. reactions of RSH (R = Et, Ph) with (CO)3Mo(μ-dppm)2Ru(CO)3 (1) in toluene yield (CO)2Mo(μ-SR)(μ-CO)(μ-dppm)2Ru(H)(CO) [R = Et (3); Ph (4)], which were characterized by elemental anal., 1H NMR and IR spectroscopies and, in the case of 3, by x-ray crystallog. The complexes contain a trans,trans-Mo(μ-dppm)2Ru unit with a bridging thiolate, a terminal hydride at the Ru, three terminal CO ligands (two at the Mo, and one at the Ru), and one semi-bridged CO closer to the Mo. [on SciFinder(R)] |
