Title | Pd-arylurea complexes for the Heck arylation of crotonic and cinnamic substrates |
Publication Type | Journal Article |
Year of Publication | 2013 |
Authors | Smith, MR, Kim, JYun, Ciufolini, MA |
Journal | TETRAHEDRON LETTERS |
Volume | 54 |
Pagination | 2042-2045 |
Date Published | APR 17 |
ISSN | 0040-4039 |
Abstract | A catalyst consisting of the 1:2 complex of Pd(OAc)(2) (1 mol %) with N-(4-carbethoxy)-phenylurea promotes the Heck arylation of a range of crotonic and cinnamic substrates, including aldehydes, ketones, esters, and nitriles, with electron-rich-but not electron-deficient-aryl iodides. (c) 2013 Elsevier Ltd. All rights reserved. |
DOI | 10.1016/j.tetlet.2013.01.077 |
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