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Protonated dipyrromethenes and tetrahalozinc anions as synthons in the solid state

TitleProtonated dipyrromethenes and tetrahalozinc anions as synthons in the solid state
Publication TypeJournal Article
Year of Publication2004
AuthorsShin, JY, Dolphin, D, Patrick, BO
JournalCrystal Growth & Design
Volume4
Pagination659-661
Date PublishedJul-Aug
Type of ArticleEditorial Material
ISBN Number1528-7483
KeywordsCHEMISTRY, DESIGN, LIGANDS
Abstract

(HL)(2)ZnBr4 and (HL)(2)ZnCl4 were prepared by the addition of HBr or HCl into a CH3CN solution of Zn(II)L-2, and their structures were determined by X-ray diffraction analysis. The X-ray crystallographic data show super structures that have hydrogen bonds between the tetrahalozinc anions ([ZnX4](2-)) and the protonated dipyrromethene cations.

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