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PURE ROTATIONAL TRANSITIONS OF SILVER-CHLORIDE PREPARED IN AN ELECTRIC-DISCHARGE, OBSERVED WITH A CAVITY MICROWAVE FOURIER-TRANSFORM SPECTROMETER

TitlePURE ROTATIONAL TRANSITIONS OF SILVER-CHLORIDE PREPARED IN AN ELECTRIC-DISCHARGE, OBSERVED WITH A CAVITY MICROWAVE FOURIER-TRANSFORM SPECTROMETER
Publication TypeJournal Article
Year of Publication1992
AuthorsStyger, C, Gerry, MCL
JournalChemical Physics Letters
Volume188
Pagination213-216
Date PublishedJan
Type of ArticleArticle
ISBN Number0009-2614
KeywordsSPECTRA
Abstract

Pure rotational transitions of silver chloride generated in an electric discharge have been observed using a cavity microwave Fourier-transform spectrometer. This is the first report of the successful use of this method to generate a metal compound for microwave spectroscopy. The high resolution of the instrument has permitted an improvement of two orders of magnitude in the precision of the Cl-35 nuclear quadrupole coupling constants.

URL<Go to ISI>://A1992HB67000011