Research & Teaching Faculty

  1. Research & Teaching Faculty
  2. Department Publications
  3. THE REGIOSPECIFIC REACTION OF DIPHENYLACETYLENE WITH BIS(CYCLOPENTADIENYL)(O-FLUOROBENZYNE)TITANIUM - THE CRYSTAL-STRUCTURE OF THE CR(CO)(3), DERIVATIVE OF L,L-BIS(CYCLOPENTADIENYL)2,3-DIPHENYL-7-FLUOROTITANOLE

THE REGIOSPECIFIC REACTION OF DIPHENYLACETYLENE WITH BIS(CYCLOPENTADIENYL)(O-FLUOROBENZYNE)TITANIUM - THE CRYSTAL-STRUCTURE OF THE CR(CO)(3), DERIVATIVE OF L,L-BIS(CYCLOPENTADIENYL)2,3-DIPHENYL-7-FLUOROTITANOLE

TitleTHE REGIOSPECIFIC REACTION OF DIPHENYLACETYLENE WITH BIS(CYCLOPENTADIENYL)(O-FLUOROBENZYNE)TITANIUM - THE CRYSTAL-STRUCTURE OF THE CR(CO)(3), DERIVATIVE OF L,L-BIS(CYCLOPENTADIENYL)2,3-DIPHENYL-7-FLUOROTITANOLE
Publication TypeJournal Article
Year of Publication1993
AuthorsButler, IR, Cullen, WR, Einstein, FWB, Jones, RH
JournalJournal of Organometallic Chemistry
Volume462
PaginationC6-C9
Date PublishedDec
Type of ArticleNote
ISBN Number0022-328X
KeywordsCYCLOALKYNES, METAL-COMPLEXES
Abstract

{Diphenylacetylene reacts with the pyrolysis product of bis(cyclopentadienyl)-bis(o-fluorophenyl)titanium to afford predominantly one isomer of the expected titanole. The crystal structure of the Cr(CO)(3) derivative 4 of the titanole shows that the fluorine is in the 7-position indicating that attack of the acetylene on the benzyne intermediate occurs along the less sterically hindered path. Compound 4: monoclinic, Cc
URL<Go to ISI>://A1993MM53500050