Title | RHENIUM(V) AND TECHNETIUM(V) COMPLEXES OF BIS(O-HYDROXYPHENYL)PHENYLPHOSPHINE (PO2(2-)) AND (O-HYDROXYPHENYL)DIPHENYLPHOSPHINE (PO-) LIGANDS |
Publication Type | Journal Article |
Year of Publication | 1995 |
Authors | Luo, HY, Setyawati, I, Rettig, SJ, Orvig, C |
Journal | Inorganic Chemistry |
Volume | 34 |
Pagination | 2287-2299 |
Date Published | Apr |
Type of Article | Article |
ISBN Number | 0020-1669 |
Keywords | CHEMISTRY, COORDINATION, RAY CRYSTAL-STRUCTURE, TERTIARY PHOSPHINES |
Abstract | {A modified preparation of the hydrochloride adduct of the potentially tridentate ligand bis(o-hydroxyphenyl)-phenylphosphine (abbreviated H2PO2 . HCl) is described. From this ligand and a potentially bidentate analog, (o-hydroxyphenyl)diphenylphosphine (HPO), POxx- (x = 1, 2) complexes of rhenium(V) and technetium(V) were prepared by metathesis reactions with the appropriate metal(V) precursor and/or by reduction/ligand-exchange reactions with ammonium perrhenate or pertechnetate. The new complexes fall into four categories: bis(PO) complexes (MOCl(PO)(2) |
URL | <Go to ISI>://A1995QV82400008 |