| Title | Rhodium(I)-(N-heterocyclic carbene)-diphosphine complexes |
| Publication Type | Journal Article |
| Year of Publication | 2009 |
| Authors | Sun, HS, Yu, XY, Marcazzan, P, Patrick, BO, James, BR |
| Journal | Canadian Journal of Chemistry-Revue Canadienne De Chimie |
| Volume | 87 |
| Pagination | 1248-1254 |
| Date Published | Sep |
| Type of Article | Article |
| ISBN Number | 0008-4042 |
| Keywords | C-H ACTIVATION, CATALYTIC-ACTIVITY, HETEROCYCLIC CARBENE COMPLEXES, HYDROFORMYLATION, HYDROGENATION REACTIONS, HYDROSILYLATION, iridium complexes, LIGANDS, phosphine, RHODIUM(I) COMPLEXES |
| Abstract | {Les reactions du [RhCl(COE)(IPr)](2) (1) et du [RhCl(COE)(IMes)](2) (2) [COE = cyclooctene; IPr = N,N’-bis(2,6-diisopropylphenyl)imidazoline-2-ylidene; IMes = N,N’-bis(2,4,6-trimethylphenyl)imidazoline-2-ylidene] avec les diphosphines Ph2P(CH2)(n)PPh2 et 1,2-bis(diphenylphosphino)benzene (dppbz) conduisent a la formation de complexes carbene N-heterocyclique (NHC) - diphosphine - rhodium(I): RhCl(NHC)[Ph2P(CH2)(n)PPh2] [NHC = IPr |
| URL | <Go to ISI>://000269751100008 |
