Research & Teaching Faculty

  1. Research & Teaching Faculty
  2. Department Publications
  3. ROTATIONAL ANALYSIS OF THE HIGH-RESOLUTION INFRARED-SPECTRA OF THE NU-4 AND NU-5 BANDS OF FORMYL CHLORIDE

ROTATIONAL ANALYSIS OF THE HIGH-RESOLUTION INFRARED-SPECTRA OF THE NU-4 AND NU-5 BANDS OF FORMYL CHLORIDE

TitleROTATIONAL ANALYSIS OF THE HIGH-RESOLUTION INFRARED-SPECTRA OF THE NU-4 AND NU-5 BANDS OF FORMYL CHLORIDE
Publication TypeJournal Article
Year of Publication1994
AuthorsFrench, JL, Clouthier, DJ, Chan, CP, Ma, ESF, Lai, VWM, Merer, AJ, Judge, RH
JournalJournal of Molecular Spectroscopy
Volume168
Pagination99-108
Date PublishedNov
Type of ArticleArticle
ISBN Number0022-2852
KeywordsCL ATOM, FTIR, OXIDATION
Abstract

The high-resolution infrared spectra of the low-lying nu4 and nu5 fundamentals of the transient molecule formyl chloride, HCOCl, are reported. Both thype A/B hybrid bands have been analyzed in detail, providing rotational assignments for the HCO Cl-35 and HCO Cl-37 isotopomers. The excited state rotational and centrifugal distortion constants have been determined by fitting assignments over a wide range of J and K(a) values. No perturbations were detected in either band. (C) 1991 Academic Pess, Inc.
URL<Go to ISI>://A1994PM71600007