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Selectivity of potentially hexadentate amine phenols for Ga3+ and In3+ in aqueous solution

TitleSelectivity of potentially hexadentate amine phenols for Ga3+ and In3+ in aqueous solution
Publication TypeJournal Article
Year of Publication1996
AuthorsWong, E, Caravan, P, Liu, S, Rettig, SJ, Orvig, C
JournalInorganic Chemistry
Volume35
Pagination715-724
Date PublishedJan
Type of ArticleArticle
ISBN Number0020-1669
KeywordsACID, aluminum, CHELATION, CRYSTAL, GA-68, gallium, IONS, LIGANDS, STABILITIES, TRIVALENT METAL-COMPLEXES
Abstract

{A new series of linear N4O2 amine phenols (H(2)badd, H(2)Brbadd, and H(2)Clbadd) based on N,N’-bis(3-aminopropyl)-ethylenediamine (tnentn) were prepared and characterized by spectroscopic techniques. Monocationic hexadentate metal complexes with the tnentn-based amine phenols were obtained from the reactions of Ga3+ and In3+ with the Linear amine phenol in the presence of a weak base (acetate). The molecular structure of [Ga(Brbadd)]ClO4 has been determined by X-ray crystallography; crystals of [Ga(Brbadd)][ClO4] (C22H30Br2ClGaN4O6) are orthorhombic: a = 12.462(1) Angstrom

URL<Go to ISI>://A1996TT71700029