| Title | Solvolysis reactions in liquid antimony (V) fluoride. A convenient and versatile synthetic method |
| Publication Type | Journal Article |
| Year of Publication | 1996 |
| Authors | Wang, C, Hwang, G, Siu, SC, Aubke, F, Bley, B, Bodenbinder, M, Bach, C, Willner, H |
| Journal | European Journal of Solid State and Inorganic Chemistry |
| Volume | 33 |
| Pagination | 917-930 |
| Type of Article | Article |
| ISBN Number | 0992-4361 |
| Keywords | CATIONS, CRYSTAL, FLUOROSULFATES, MAGNETIC-PROPERTIES, MAS NMR-SPECTRA, MOLECULAR-STRUCTURE, NOBLE-METALS, TRIS(FLUOROSULFATE), UNDECAFLUORODIANTIMONATE(V), VIBRATIONAL-SPECTRA |
| Abstract | {Solvolysis reactions of various fluorosulfates in liquid antimony (V) fluoride allow the synthesis of a wide range of fluoroantimonate (V) salts with main group, organometallic and transition metal cations. In the presence of carbon monoxide, CO, at pressures of 0.5 to 2.0 atmospheres a new group of homoleptic carbonyl cations of electronrich metals (Hg, Au, Pt, Pd, Ir, Ru, and Os) form with [Sb2F11](-) as anion. The salts show relatively high thermal stability (> 100 degrees C). The geometries of the cations [Au(CO)(2)](+), [Hg(CO)(2)](2+) (linear) and [M(CO)(4)](2+) |
| URL | <Go to ISI>://A1996VK52700012 |
