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Spontaneous Hierarchical Assembly of Crown Ether-like Macrocycles into Nanofibers and Microfibers Induced by Alkali-Metal and Ammonium Salts.

TitleSpontaneous Hierarchical Assembly of Crown Ether-like Macrocycles into Nanofibers and Microfibers Induced by Alkali-Metal and Ammonium Salts.
Publication TypeJournal Article
Year of Publication2010
AuthorsHui, JK-H, Frischmann, PD, Tso, C-H, Michal, CA, MacLachlan, MJ
JournalChemistry–A European Journal
Volume16
Pagination2453-2460, S2453/1-S2453/11
Date Published2010///
ISBN Number0947-6539
Keywordsspontaneous hierarchical assembly crown ether like macrocycle nanofiber microfiber
Abstract

Schiff base macrocycle 1, which has a crown ether like central pore, was combined with different alkali-metal and ammonium salts in chloroform, resulting in one-dimensional supramol. aggregates. The ion-induced self-assembly was studied with solid-state NMR spectroscopy, transmission electron microscopy (TEM), SEM, and at. force microscopy (AFM). It was found that the lengths and widths of the superstructures depend on the cation and counter-anion of the salts. Among the salts being used, Na+ and NH4+ ions with BF4- ions showed the most impressive fibrous structures that can grow up to 1 μm in diam. and hundreds of microns in length. In addn., the size of the fibers can be controlled by the evapn. rate of the solvent. A new macrocycle with bulky triptycenyl substituents that prevent supramol. assembly was prepd. and did not display any nanofibers with alkali-metal ions in chloroform when studied with TEM. [on SciFinder(R)]