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  3. STRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .59. REACTION OF 2 STERICALLY HINDERED N,N’-DIHYDROXYAMINALS WITH PHENYLBORONIC ACID, AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF THE RESULTING 1,3,5-TRIOXA-6,8-DIAZA-2,4-DIBORACYCLOOCTANES AND ONE OF THE ADDU

STRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .59. REACTION OF 2 STERICALLY HINDERED N,N’-DIHYDROXYAMINALS WITH PHENYLBORONIC ACID, AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF THE RESULTING 1,3,5-TRIOXA-6,8-DIAZA-2,4-DIBORACYCLOOCTANES AND ONE OF THE ADDU

TitleSTRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .59. REACTION OF 2 STERICALLY HINDERED N,N’-DIHYDROXYAMINALS WITH PHENYLBORONIC ACID, AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF THE RESULTING 1,3,5-TRIOXA-6,8-DIAZA-2,4-DIBORACYCLOOCTANES AND ONE OF THE ADDU
Publication TypeJournal Article
Year of Publication1993
AuthorsKliegel, W, Lubkowitz, G, Rettig, SJ, Trotter, J
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume71
Pagination2129-2138
Date PublishedDec
Type of ArticleArticle
ISBN Number0008-4042
Abstract

{The syntheses of the sterically hindered N,N’-dihydroxyaminals; N,N’-bis(1-ethoxycarbonyl-1-methylethyl)-N,N’ -dihydroxymethanediamine, 1b, and N,N’-bis(1,1-dimethylethyl)-N,N’-dihydroxymethanediamine, 1c, and their reactions with phenylboronic acid to yield the 1,3,5-trioxa-6,8-diaza-2,4-diboracyclooctanes 3 and 4, respectively, are described. Crystals of 1b are tetragonal
URL<Go to ISI>://A1993MV33000019