| Title | Structural studies of organoboron compounds, Part 72 - Nitrones and oximes of bifunctional carbonyl compounds and their reaction products with diarylborinic acids. Crystal and molecular structure of examples of five-, six-, and seven-membered boron chelat |
| Publication Type | Journal Article |
| Year of Publication | 2000 |
| Authors | Kliegel, W, Lubkowitz, G, Pokriefke, JO, Rettig, SJ, Trotter, J |
| Journal | Canadian Journal of Chemistry-Revue Canadienne De Chimie |
| Volume | 78 |
| Pagination | 1325-1344 |
| Date Published | Oct |
| Type of Article | Article |
| ISBN Number | 0008-4042 |
| Keywords | carboxynitrones, carboxyoximes, CHEMISTRY, COBALT(III), crystal structure, DERIVATIVES, diarylboron chelates, DIPHENYLBORINIC ACID, hydroxynitrones, HYDROXYOXIME STRUCTURE, hydroxyoximes, LIGAND, METAL-COMPLEXES, N-(2-HYDROXYALKYL)NITRONES, ORGANOBORON COMPOUNDS, RING-CHAIN ISOMERISM |
| Abstract | {Synthesis has been carried out of diarylboron chelates of 2- and 3-hydroxynitrones, of 2- and 3-hydroxyoximes, and of 2-carboxynitrones and a 2-carboxyoxime. The structures have been determined from spectroscopic data and from X-ray analyses of 5d, 9a, 11b, and 19. Crystals (at 180 K) of 5d are monoclinic |
| URL | <Go to ISI>://000090015600009 |