| Title | Synthesis and structural studies of chiral indium(III) complexes supported by tridentate diaminophenol ligands. |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Acosta-Ramirez, A, Douglas, AF, Yu, I, Patrick, BO, Diaconescu, PL, Mehrkhodavandi, P |
| Journal | Inorganic Chemistry (Washington, DC, United States) |
| Volume | 49 |
| Pagination | 5444 - 5452 |
| Date Published | 2010/// |
| ISBN Number | 0020-1669 |
| Keywords | crystal structure dimethylindium dihaloindium cyclohexanediamine phenolate tridentate complex, hydrolysis binuclear indium cyclohexanediamine phenolate tridentate complex, indium organometallic cyclohexanediamine phenol tridentate complex prepn structure, mol structure dimethylindium dihaloindium cyclohexanediamine phenolate tridentate complex, protonolysis substitution prepn dimethylindium dihaloindium cyclohexanediamine phenolate tridentate complex |
| Abstract | {Indium trans-cyclohexanediamine-phenol tridentate di-Me, dihalide, and alkoxy-bridged complexes were prepd. and characterized. Protonolysis of InMe3 with the phenolic group of the ligand, trans-2-(Me2N)C6H10NHCH2C6H2-3,5-tBu2-2-OH (H-NNO) gave pentacoordinate indium complexes [(NNO)InMe2] (1) and [Me2ClIn(μ-NNO)InMe2] (2) with meridional NNO-frame. Substitution of potassium phenolate K(NNO) with InX3 gave dihalides [(NNO)InX2] (3-5 |
