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Synthesis and structure of [Mo(CO)(4)(2)(cis-mu-F2SbF4)(3)](x)[Sb2F11](x): An ionic coordination polymer

TitleSynthesis and structure of [Mo(CO)(4)(2)(cis-mu-F2SbF4)(3)](x)[Sb2F11](x): An ionic coordination polymer
Publication TypeJournal Article
Year of Publication1999
AuthorsBrochler, R, Freidank, D, Bodenbinder, M, Sham, IHT, Willner, H, Rettig, SJ, Trotter, J, Aubke, F
JournalInorganic Chemistry
Volume38
Pagination3684-3687
Date PublishedAug
Type of ArticleArticle
ISBN Number0020-1669
KeywordsANIONS, COMPLEXES, CRYSTAL, FLUORIDE, FLUOROSULFATE, MOLYBDENUM, UNDECAFLUORODIANTIMONATE(V)
Abstract

{The oxidation of molybdenum hexacarbonyl, Mo(CO)(6), by antimony(V) fluoride, SbF5, at 60 degrees C in an excess of liquid SbF5, produces polymeric [{Mo(CO)(4)}(2)(cis-mu-F2SbF4)(3)](x)[Sb2F11](x) as the main product. Recrystallization from HF-SbF5 produces orange prismatic crystals, suitable for a single-crystal X-ray diffraction study. Crystals of [{Mo(CO)(4)}(2)(cis-mu-F2SbF4)(3)](x)[Sb2F11](x) are monoclinic, space group P2(1)/c (No. 14)

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