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  3. Synthesis of C-aryl-N-(2-hydroxyphenylmethyl)-nitrones and their reaction with diphenylborinic or carboxylic acid derivatives. Crystal and molecular structures of a free nitrone ligand and its diphenyl-boron chelate

Synthesis of C-aryl-N-(2-hydroxyphenylmethyl)-nitrones and their reaction with diphenylborinic or carboxylic acid derivatives. Crystal and molecular structures of a free nitrone ligand and its diphenyl-boron chelate

TitleSynthesis of C-aryl-N-(2-hydroxyphenylmethyl)-nitrones and their reaction with diphenylborinic or carboxylic acid derivatives. Crystal and molecular structures of a free nitrone ligand and its diphenyl-boron chelate
Publication TypeJournal Article
Year of Publication1997
AuthorsKliegel, W, Metge, J, Rettig, SJ, Trotter, J
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume75
Pagination1830-1843
Date PublishedDec
Type of ArticleArticle
ISBN Number0008-4042
Keywords2-METHYLINDOLE, ALDEHYDES, aromatic aldonitrones, C-13 NMR-SPECTRA, crystal structures, HYDROGEN-BOND, N-(2-HYDROXYALKYL)NITRONES, N-(3-HYDROXYALKYL)NITRONES, N-OXIDE, NITROSOBENZENES, ORGANOBORON COMPOUNDS, RING-CHAIN ISOMERISM
Abstract

{The syntheses of a number of aromatic aldonitrones of N-(2-hydroxyphenylmethyl)hydroxylamine and their subsequent reactions with diphenylborinic or carboxylic acid derivatives are reported. Crystals of 8-(4-dimethylaminophenylmethylene)-6,6-diphenyl-5,7-dioxa-8-azonia-6-bor ata-5H-6,7,8,9-tetrahydrobenzocycloheptene, 2b, are triclinic
URL<Go to ISI>://000071734500005