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  3. SYNTHESIS, MOLECULAR-STRUCTURE, AND VIBRATIONAL-SPECTRA OF CYCLO-BIS(MU-CARBONYL)DIPALLADIUM(I) FLUOROSULFATE, [C-PD2(MU-CO)2](SO3F)2

SYNTHESIS, MOLECULAR-STRUCTURE, AND VIBRATIONAL-SPECTRA OF CYCLO-BIS(MU-CARBONYL)DIPALLADIUM(I) FLUOROSULFATE, [C-PD2(MU-CO)2](SO3F)2

TitleSYNTHESIS, MOLECULAR-STRUCTURE, AND VIBRATIONAL-SPECTRA OF CYCLO-BIS(MU-CARBONYL)DIPALLADIUM(I) FLUOROSULFATE, [C-PD2(MU-CO)2](SO3F)2
Publication TypeJournal Article
Year of Publication1994
AuthorsWang, CQ, Bodenbinder, M, Willner, H, Rettig, S, Trotter, J, Aubke, F
JournalInorganic Chemistry
Volume33
Pagination779-786
Date PublishedFeb
Type of ArticleArticle
ISBN Number0020-1669
KeywordsCARBONYL HALIDES, COMPLEXES, CRYSTAL-STRUCTURE, palladium
Abstract

{The synthesis, molecular structure, and complete vibrational spectrum of cyclo-bis(mu-carbonyl)dipalladium(I) fluorosulfate, [c-Pd2(mu-CO)2] (SO3F)2, are reported. The synthesis is achieved by reductive decomposition of Pd-(CO)2(SO3F)2 in fluorosulfuric acid, HSO3F; at 25-degrees-C, long orange-red needles form over a period of about 3 weeks. The compound is stable up to 157-degrees-C (the decomposition point). The molecular structure is solved by single-crystal X-ray diffraction. Crystals of [Pd2(mu-CO)2](SO3F)2 are monoclinic, C2/c; a = 11.495(1)
URL<Go to ISI>://A1994MX86000026