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Synthesis, molecular structure, and vibrational spectra of mer-tris(carbonyl)iridium(III)fluorosulfate, mer-Ir(CO)(3)(SO3F)(3)

TitleSynthesis, molecular structure, and vibrational spectra of mer-tris(carbonyl)iridium(III)fluorosulfate, mer-Ir(CO)(3)(SO3F)(3)
Publication TypeJournal Article
Year of Publication1996
AuthorsWang, CQ, Lewis, AR, Batchelor, RJ, Einstein, FWB, Willner, H, Aubke, F
JournalInorganic Chemistry
Volume35
Pagination1279-1285
Date PublishedFeb
Type of ArticleArticle
ISBN Number0020-1669
KeywordsDERIVATIVES, FLUOROSULFATES, GOLD, palladium, SYSTEM, UNDECAFLUORODIANTIMONATE(V)
Abstract

{Addition of carbon monoxide (0.5-2 atm) to iridium(III) fluorosulfate, Ir(SO3F)(3), dissolved in HSO3F over 4 days and at 60 degrees C, results in the quantitative formation of tris(carbonyl)iridium(III) fluorosulfate Ir(CO)(3)(SO3F)(3) Slow evaporation of the solvent produces single crystals of mer-Ir(CO)(3)(SO3F)(3). Crystal structure data for mer-Ir(CO)(3)(SO3F)(3): monoclinic, space group P2(1)/c

URL<Go to ISI>://A1996TY26000029