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  3. THERMOLYSIS OF OS3(CO)10[FE(ETA-C5H4PPRI2)2] - CRYSTAL AND MOLECULAR-STRUCTURES OF (MU-H)OS3(CO)8[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRICHMECH2CO)], (MU-H)OS3(CO)9[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRI)], AND (MU-H)2OS3(CO)8[ETA-3-MU-(ETA-C5H4PPRI2)FE(ETA-C5H3PPRI

THERMOLYSIS OF OS3(CO)10[FE(ETA-C5H4PPRI2)2] - CRYSTAL AND MOLECULAR-STRUCTURES OF (MU-H)OS3(CO)8[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRICHMECH2CO)], (MU-H)OS3(CO)9[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRI)], AND (MU-H)2OS3(CO)8[ETA-3-MU-(ETA-C5H4PPRI2)FE(ETA-C5H3PPRI

TitleTHERMOLYSIS OF OS3(CO)10[FE(ETA-C5H4PPRI2)2] - CRYSTAL AND MOLECULAR-STRUCTURES OF (MU-H)OS3(CO)8[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRICHMECH2CO)], (MU-H)OS3(CO)9[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRI)], AND (MU-H)2OS3(CO)8[ETA-3-MU-(ETA-C5H4PPRI2)FE(ETA-C5H3PPRI
Publication TypeJournal Article
Year of Publication1993
AuthorsCullen, WR, Rettig, SJ, Zheng, TC
JournalOrganometallics
Volume12
Pagination688-696
Date PublishedMar
Type of ArticleArticle
ISBN Number0276-7333
KeywordsCOMPLEXES, COORDINATION, OSMIUM, TRIOSMIUM CLUSTERS, X-ray structures
Abstract

{The pyrolysis of Os3(CO)10[Fc’(PPri2)2] (Fc’ = (17-C5H4)2Fe) in octane for 7.5 h affords (mu-H)Os3(CO)8[mu-(eta-C5H4Pri2)Fe(eta-C5PriCHMeCH2CO)], 5, (mu-H)Os3(CO)9[mu-(eta-C5H4PPri2)Fe(eta-C5H4PPri)], 6, (mu-H)2083(CO)8[mu-[eta-C5H4Pri2)Fe(eta-C5H3PPri)], 7, (mu-H)083(CO)8[mu-(eta-C5H4PPri2) Fe(eta-C5H4PPriCHMeCH2CO)], 8, (mu-H)2083(CO)8[(eta-C5H4PPri2)Fe(eta-C5H3PPri)], 9, and (A-H)2Os3(CO)8[(eta-C5H4PPri)Fe(eta-C5H3PPri2)],10. X-ray data: 5,monoclinic,space group P2(1)/a (No. 14)
URL<Go to ISI>://A1993KR05600019