| Title | The unexpected formation of a tetradentate tripyrrolic complex of nickel(II) |
| Publication Type | Journal Article |
| Year of Publication | 1996 |
| Authors | Bruckner, C, Mar, EK, Rettig, SJ, Dolphin, D |
| Journal | Chemische Berichte |
| Volume | 129 |
| Pagination | 1195-1198 |
| Date Published | Oct |
| Type of Article | Article |
| ISBN Number | 0009-2940 |
| Keywords | CHEMISTRY, imine hydrolysis, macrocycle, PORPHOCYANINE, pyrrolic nickel(II) complexes, template effect |
| Abstract | (2-Pyrolylmethane)(2-pyrrolylmethyl)imine (2) and an equimolar amount of 2-formylpyrrole give, in the presence of nickel (II) in hot methanol, the novel tripyrrolic nickel(II) complex [SP-4]-[(2-dipyrrinato-kappa(2)N,N’-methyl)(2-pyrrolylmethanato-kappa N’’’imine-kappa N’’’]nickel(II) (4). This planar complex had been characterized by X-ray crystallography, a mechanism for its formation is proposed and its mass spectral behavior is discussed. |
| URL | <Go to ISI>://A1996VN63600008 |
