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Why ALC mu SR is superior for gas-phase radical spectroscopy

TitleWhy ALC mu SR is superior for gas-phase radical spectroscopy
Publication TypeJournal Article
Year of Publication1997
AuthorsDilger, H, Roduner, E, Stolmar, M, Reid, ID, Fleming, DG, Arseneau, DJ, Pan, JJ, Senba, M, Shelley, M
JournalHyperfine Interactions
Volume106
Pagination137-142
Type of ArticleProceedings Paper
ISBN Number0304-3843
KeywordsHYPERFINE CONSTANTS, ORGANIC FREE-RADICALS, SPECTRA, SPIN RELAXATION
Abstract

ALC mu SR spectra of the muonated ethyl and cyclohexadienyl radicals in the gas phase are reported. They have surprisingly narrow lines for a magnetic resonance type technique under conditions near ambient temperature and near 1 atmosphere pressure. The main reason for this behaviour is the dramatic reduction of electron spin relaxation in high magnetic fields.

URL<Go to ISI>://A1997XB05500019