Title | AN XPS STUDY OF POLY-BIS(MU-DI-N-ALKYLPHOSPHINATO)COPPER(II) COMPOUNDS |
Publication Type | Journal Article |
Year of Publication | 1991 |
Authors | Hu, H, Du, JL, Thompson, RC, Frost, DC |
Journal | Inorganica Chimica Acta |
Volume | 179 |
Pagination | 113-115 |
Date Published | Jan |
Type of Article | Article |
ISBN Number | 0020-1693 |
Keywords | photoelectron |
Abstract | X-ray photoelectron spectroscopic (XPS) studies are reported on nine poly-copper(II) di-n-alkylphosphinates, Cu[(C(n)H2n+1)2PO2]2 (where n = 2, 4 and 6 and two polymorphs each of the compounds where n = 8, 10 and 12). While there is very little variation in the C(1s1/2), O(1s1/2) and P(2p3/2) binding energies (BEs) amongst the nine compounds, significant differences are seen in the Cu(2p3/2) and Cu(2p1/2) BEs. These latter BEs are discussed in relation to the known structures and magnetic properties of these materials. |
URL | <Go to ISI>://A1991FB37100019 |
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