| Title | Zirconium bis(pyridonate): a modified amidate complex for enhanced substrate scope in aminoalkene cyclohydroamination. |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Bexrud, JA, Schafer, LL |
| Journal | Dalton Transactions |
| Volume | 39 |
| Pagination | 361 - 363 |
| Date Published | 2010/// |
| ISBN Number | 1477-9226 |
| Keywords | aminoalkene cyclohydroamination catalyst zirconium amidate amido, crystal structure zirconium pyridonate amido, zirconium pyridonate amido prepn cyclohydroamination catalyst aminoalkene |
| Abstract | A new bis(amidate)zirconium bis(amido) hydroamination pre-catalyst [ZrL2(NMe2)2] using 6-tert-butyl-3-phenyl-2-pyridone as a proligand (HL) was prepd. and crystallog. characterized. This rare example of an early transition metal complex incorporating a 2-pyridonate deriv. as an ancillary ligand is an effective catalyst for the cyclohydroamination of aminoalkenes, including more challenging substrates bearing unactivated internal C:C bonds. [on SciFinder(R)] |
