Title | BIS(DIPHENYLPHOSPHINO)METHANE COMPLEXES OF PALLADIUM AS CATALYSTS FOR HYDROSILYLATION OF OLEFINS BY TRICHLOROSILANE |
Publication Type | Journal Article |
Year of Publication | 1992 |
Authors | Gulinski, J, James, BR |
Journal | Journal of Molecular Catalysis |
Volume | 72 |
Pagination | 167-171 |
Date Published | Mar |
Type of Article | Article |
ISBN Number | 0304-5102 |
Keywords | BOND, CRYSTAL, HYDROGEN-SULFIDE, INSERTION, metal complexes, Pd(I), PHOSPHINE COMPLEXES |
Abstract | Mononuclear Pd(II), and dinuclear Pd(O) and Pd(I) complexes containing bis(diphenylphosphino)methane catalyze the addition of trichlorosilane to the olefinic bond of hexene-1, styrene and vinyltrichlorosilane. Activity relationships for limited data at 80 and 120-degrees-C suggest that in each case mononuclear Pd(O) species might act as a catalyst precursor. |
URL | <Go to ISI>://A1992HT94000006 |
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