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Bis(ligand) rhenium(V) and technetium(V) complexes of two naturally occurring binding moieties (oxazoline and thiazoline)

TitleBis(ligand) rhenium(V) and technetium(V) complexes of two naturally occurring binding moieties (oxazoline and thiazoline)
Publication TypeJournal Article
Year of Publication1996
AuthorsShuter, E, Hoveyda, HR, Karunaratne, V, Rettig, SJ, Orvig, C
JournalInorganic Chemistry
Volume35
Pagination368-372
Date PublishedJan
Type of ArticleArticle
ISBN Number0020-1669
KeywordsCOORDINATION CHEMISTRY, RADIOPHARMACEUTICALS, RAY CRYSTAL-STRUCTURE, SIDEROPHORE, TC-99M
Abstract

{Attempts to prepare tris(ligand) metal complexes of technetium in intermediate oxidation states with potentially bidentate oxazoline- and thiazoline-containing ligands were unsuccessful; when pertechnetate was reduced in the presence of excess ligand, TcO2 . xH(2)O was produced. Instead, by reaction with preformed M . O cores, a series of oxotechnetium(V) and oxorhenium(V) complexes of the formula MOXL(2) (M = Re
URL<Go to ISI>://A1996TR24000018