Title | A formal construction of fasicularin |
Publication Type | Journal Article |
Year of Publication | 2003 |
Authors | Fenster, MDB, Dake, GR |
Journal | Organic Letters |
Volume | 5 |
Pagination | 4313-4316 |
Date Published | Nov |
Type of Article | Article |
ISBN Number | 1523-7060 |
Keywords | (+/-)-LEPADIFORMINE, CROSS-COUPLING, CYLINDRICINE, DIELS-ALDER REACTION, DIPOLAR CYCLOADDITION, ENANTIOMER, KETONES, MARINE ALKALOID LEPADIFORMINE, NATURAL, reaction, REARRANGEMENT, STEREOSELECTIVE CONSTRUCTION |
Abstract | Our synthetic approach toward fasicularin is presented. Key steps in this construction are a siloxy-epoxide semipinacol rearrangement, a B-alkyl Suzuki reaction and an intramolecular S(N)2 reaction. |
URL | <Go to ISI>://000186468000019 |
