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MER-TRIS[2-(5-BROMO-2-HYDROXYPHENYL)-2-OXAZOLINATO]ALUMINIUM(III) METHANOL SOLVATE

TitleMER-TRIS[2-(5-BROMO-2-HYDROXYPHENYL)-2-OXAZOLINATO]ALUMINIUM(III) METHANOL SOLVATE
Publication TypeJournal Article
Year of Publication1994
AuthorsHoveyda, HR, Orvig, C, Rettig, SJ
JournalActa Crystallographica Section C-Crystal Structure Communications
Volume50
Pagination1906-1909
Date PublishedDec
Type of ArticleArticle
ISBN Number0108-2701
Abstract

The title complex, (OC-6-21)-tris[4-bromo-2-(4,5-dihydro-1 ,3-oxazol-2-yl)phenolato-N,O]aluminium(III) methanol solvate, [Al(C9H7?BrNO2)(3)].CH4O, has a slightly distorted octahedral coordination geometry with a meridional arrangement of the ligands. Pertinent Al-O and Al-N bond distances are 1.839 (2)-1.876 (2) and 2.015 (3)-2.024 (3) Angstrom, respectively. The methanol solvent is hydrogen bonded to one of the coordinated O atoms.
URL<Go to ISI>://A1994PX93100030