Research & Teaching Faculty

THE ELECTRONIC-SPECTRUM OF CARBON-DIOXIDE - DISCRETE AND CONTINUUM PHOTOABSORPTION OSCILLATOR-STRENGTHS (6-203 EV)

TitleTHE ELECTRONIC-SPECTRUM OF CARBON-DIOXIDE - DISCRETE AND CONTINUUM PHOTOABSORPTION OSCILLATOR-STRENGTHS (6-203 EV)
Publication TypeJournal Article
Year of Publication1993
AuthorsChan, WF, Cooper, G, Brion, CE
JournalCHEMICAL PHYSICS
Volume178
Pagination401-413
Date PublishedDEC 15
ISSN0301-0104
Abstract

The recently developed high resolution dipole (e, e) method, which is free of Beer-Lambert law `'line saturation'' errors, has been used to determine absolute photoabsorption oscillator strengths for the discrete electronic excitation of carbon dioxide in the energy region 6-30 eV. Low resolution dipole (e, e) measurements (1 eV fwhm) have also been made in the equivalent photon energy range 8.5-203 eV. The absolute scale of the present measurements was obtained by TRK sum-rule normalization.

DOI10.1016/0301-0104(93)85079-N