Title | Self-healing behavior of aminated polyolefins with dynamic associations |
Publication Type | Journal Article |
Year of Publication | 2023 |
Authors | Yavitt, BM, Tomkovic, T, Gilmour, DJ, Kuanr, N, van Ruymbeke, E, Schafer, LL, Hatzikiriakos, SG |
Journal | AIP CONFERENCE PROCEEDINGS |
Abstract | The rheological and self-healing behavior of a class of catalytically synthesized amine functionalized polyolefins is investigated. These materials possess tunable rheological properties and display autonomous self-healing. The linear viscoelastic properties are modelled using a tube based Time Marching Algorithm to calculate several model parameters that describe the individual chain dynamics. The self-healing response is described by findings from the reptation model as well as recent theory on associating polymer networks with reversible bonds. |